Fly into Barcelona. Both pick-up and drop-off are either at Barcelona airport or in front of the Barcelona Catalonia Plaza Hotel on Plaza Espana 10h30AM. Since it is 1 and 3/4 hour drive from El Priorat to the airport, departure flights shouldn't be scheduled any earlier than 11AM. Alternatively if you're flying from the UK you can fly into Reus airport which is only 30 minutes from the hotel.